Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene

Hüseyin KARACA

doi:https://doi.org/10.16984/saufenbilder.407781

Article Details

Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene

Authors:

Hüseyin KARACA

Main Topics:

Chemical engineering

Journal:

Sakarya University Journal of Science 2018 Vol.22 Issue 6, pp.1699-1703

Document Type:

Article

Publication Date:

11/2018

Document Language:

English

Document ID (Org No.):

2000557444

DOI:

https://doi.org/10.16984/saufenbilder.407781

Abstract:

 


Cobalt
(II) phthalocyanines carrying on the four of the peripheral positions
furan and thiophene as chalcones were sythesized. THF is used to investigate the catalytic
oxidation of 2-mercaptoethanol. The
synthesized phthalocyanines show catalytic activity on the oxidation of
2-mercaptoethanol. Cobalt (II) phthalocyanine derived by chalcone with furan
has given catalytic specifications such as turnover number TON as 16.6, initial
reaction rate as 0.293 μmol/sec
and the oxygen consumption as 10.06 μmol/min.
The other cobalt (II) phthalocyanine derived by chalcone with thiophene has
given catalytic specifications such as turnover number TON as 15.9, initial
reaction rate as 0.213 μmol/sec and
the oxygen consumption as 9.88 μmol/min. So chalcone derived phthalocyanines can be used as catalyst is oxidation
of mercaptan by air.


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Article Details

Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene

Authors: Hüseyin KARACA

Main Topics: Chemical engineering

Journal: Sakarya University Journal of Science 2018 Vol.22 Issue 6, pp.1699-1703

Document Type: Article

Publication Date: 11/2018

Document Language: English

Document ID (Org No.): 2000557444

DOI: https://doi.org/10.16984/saufenbilder.407781

Issues

Authors:

Hüseyin KARACA

Main Topics:

Chemical engineering

Journal:

Sakarya University Journal of Science 2018 Vol.22 Issue 6, pp.1699-1703

Document Type:

Article

Publication Date:

11/2018

Document Language:

English

Document ID (Org No.):

2000557444

DOI:

https://doi.org/10.16984/saufenbilder.407781