Synthesis and Spectral Investigations of Some Platinum Metals Ions Coordination Compounds of 4[N-(Furan-2'-carboxalidene)Amino]Antipyrine Thiosemicarbazone and 4[N-(3',4',5'-Trimethoxybenzalidene)Amino]Antipyrine Thiosemicarbazone

Ram K. AGARWAL; Surendra PRASAD

Article Details

Synthesis and Spectral Investigations of Some Platinum Metals Ions Coordination Compounds of 4[N-(Furan-2'-carboxalidene)Amino]Antipyrine Thiosemicarbazone and 4[N-(3',4',5'-Trimethoxybenzalidene)Amino]Antipyrine Thiosemicarbazone

Authors:

Ram K. AGARWAL | Surendra PRASAD

Publisher:

TUBITAK

Main Topics:

Applied physics

Journal:

Turkish Journal of Chemistry 2005 Vol.29 Issue 3, pp.289-298

Document Type:

Article

Publication Date:

2/2005

Document Language:

English

Document ID (Org No.):

2000729101

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

The present work describes the synthesis and spectral  properties of some platinum metals chlorides coordination compounds of  4[N-(-(furan-2'-carboxalidene)amino]antipyrine thiosemicarbazone  (FFAAPTS) and 4[N-(3',4',5'-trimethoxybenzalidene)amino]antipyrine  thiosemicarbazone (TMBAAPTS).  All the compounds have the general  composition MCl2(L) (M = Pd2+ or Pt2+ ; L = FFAAPTS or  TMBAAPTS) or MCl3(L) (M = Ru3+ , Rh3+ or Ir3+ ; L = FFAAPTS  or TMBAAPTS).  All the complexes were characterized by elemental  analyses, molar conductance, molecular weight, magnetic measurements,  and infrared and electronic spectra.  The infrared spectra suggest  that both the thiosemicarbazones behave as neutral tridentate (N,N,S)  ligands.  The magnetic and electronic spectra suggest that Pd2+ and  Pt2+ complexes are square planar, while Ru3+ , Rh3+ and  Ir3+ complexes have octahedral geometry.

 

The present work describes the synthesis and spectral  properties of some platinum metals chlorides coordination compounds of  4[N-(-(furan-2'-carboxalidene)amino]antipyrine thiosemicarbazone  (FFAAPTS) and 4[N-(3',4',5'-trimethoxybenzalidene)amino]antipyrine  thiosemicarbazone (TMBAAPTS).  All the compounds have the general  composition MCl2(L) (M = Pd2+ or Pt2+ ; L = FFAAPTS or  TMBAAPTS) or MCl3(L) (M = Ru3+ , Rh3+ or Ir3+ ; L = FFAAPTS  or TMBAAPTS).  All the complexes were characterized by elemental  analyses, molar conductance, molecular weight, magnetic measurements,  and infrared and electronic spectra.  The infrared spectra suggest  that both the thiosemicarbazones behave as neutral tridentate (N,N,S)  ligands.  The magnetic and electronic spectra suggest that Pd2+ and  Pt2+ complexes are square planar, while Ru3+ , Rh3+ and  Ir3+ complexes have octahedral geometry.

Article Details

Synthesis and Spectral Investigations of Some Platinum Metals Ions Coordination Compounds of 4[N-(Furan-2'-carboxalidene)Amino]Antipyrine Thiosemicarbazone and 4[N-(3',4',5'-Trimethoxybenzalidene)Amino]Antipyrine Thiosemicarbazone

Authors: Ram K. AGARWAL | Surendra PRASAD

Publisher: TUBITAK

Main Topics: Applied physics

Journal: Turkish Journal of Chemistry 2005 Vol.29 Issue 3, pp.289-298

Document Type: Article

Publication Date: 2/2005

Document Language: English

Document ID (Org No.): 2000729101

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Ram K. AGARWAL | Surendra PRASAD

Publisher:

TUBITAK

Main Topics:

Applied physics

Journal:

Turkish Journal of Chemistry 2005 Vol.29 Issue 3, pp.289-298

Document Type:

Article

Publication Date:

2/2005

Document Language:

English

Document ID (Org No.):

2000729101

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527