PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Nurgün BÜYÜKKIDAN; Bülent BÜYÜKKIDAN; Nedime DEMİR; Ceyda KARAHAN

Article Details

PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Authors:

Nurgün BÜYÜKKIDAN | Bülent BÜYÜKKIDAN | Nedime DEMİR | Ceyda KARAHAN

Publisher:

Kütahya Dumlupinar University

Main Topics:

Chemical engineering

Journal:

Journal of Science and Technology of Dumlupınar University 2018 Issue 041, pp.1-12

Document Type:

Article

Publication Date:

12/2018

Document Language:

Turkish

Document ID (Org No.):

2000495516

Frequency:

Quarterly

eISSN:

2687-6167

Abstract:

 


In this study the proton transfer salt (H2Meppz)(Hdipic)2 (1) was obtained by the reaction of N-methylpiperazine
(Meppz) with pyridine-2,6-dicarboxylic acid (H2dipic). The metal
complexes [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O
(2) and (H2Meppz)[Cu(dipic)2].2H2O
(3) were synthesized by the reaction
of proton transfer salt (1) with Ni(CH3COO)2.4H2O
and Cu(CH3COO)2.2H2O.
The structure of proton transfer salt (1)  was characterized by 1H and 13C
NMR, FT-IR and UV-Vis spectra and elemental analysis techniques. The structures
of the complexes have been suggested according to data obtained from FT-IR,
UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods. 

.

 

Bu çalışmada piridin-2,6-dikarboksilik asitin (H2dipic), N-metilpiperazin (Meppz) ile
reaksiyonundan proton transfer tuzu (H2Meppz)(Hdipic)2 (1) elde edilmiştir. Elde edilen
proton transfer tuzunun (1) Ni(CH3COO)2.4H2O
ve Cu(CH3COO)2.H2O ile reaksiyonundan ise metal kompleksleri [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O
(2) ve (H2Meppz)[Cu(dipic)2].2H2O
(3) sentezlenmiştir. Proton
transfer tuzunun (1) yapısı FT-IR, 1H
ve 13C NMR, ve UV-Vis spekroskopileri ve elementel analiz teknikleri
ile aydınlatılmıştır. Komplekslerin yapıları ise FT-IR, UV-Vis, ICP-OES,
manyetik duyarlılık ve elementel analiz yöntemlerinden elde edilen verilere
göre önerilmiştir. .

Article Details

PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Authors: Nurgün BÜYÜKKIDAN | Bülent BÜYÜKKIDAN | Nedime DEMİR | Ceyda KARAHAN

Publisher: Kütahya Dumlupinar University

Main Topics: Chemical engineering

Journal: Journal of Science and Technology of Dumlupınar University 2018 Issue 041, pp.1-12

Document Type: Article

Publication Date: 12/2018

Document Language: Turkish

Document ID (Org No.): 2000495516

Frequency: Quarterly

eISSN: 2687-6167

Issues

Authors:

Nurgün BÜYÜKKIDAN | Bülent BÜYÜKKIDAN | Nedime DEMİR | Ceyda KARAHAN

Publisher:

Kütahya Dumlupinar University

Main Topics:

Chemical engineering

Journal:

Journal of Science and Technology of Dumlupınar University 2018 Issue 041, pp.1-12

Document Type:

Article

Publication Date:

12/2018

Document Language:

Turkish

Document ID (Org No.):

2000495516

Frequency:

Quarterly

eISSN:

2687-6167