Host/guest inclusion system of surfactants with -cyclodextrin as a viable catalyst for one-pot synthesis of mono - and bis (indolyl)methylmalononitriles in H 2 O

Fatemeh MIRHASHEMI; Mohammad Ali AMROLLAHI

Article Details

Host/guest inclusion system of surfactants with -cyclodextrin as a viable catalyst for one-pot synthesis of mono - and bis (indolyl)methylmalononitriles in H 2 O

Authors:

Fatemeh MIRHASHEMI | Mohammad Ali AMROLLAHI

Publisher:

TUBITAK

Main Topics:

Applied physics

Journal:

Turkish Journal of Chemistry 2018 Vol.42 Issue 4, pp.988-996

Document Type:

Article

Publication Date:

8/2018

Document Language:

English

Document ID (Org No.):

2000726031

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 


 
                         In this study, encapsulation processes of cetyltrimethylammonium bromide 
(CTAB) or sodium dodecyl sulfate (SDS) monomers 
into the cavity of βββ β  β\beta -cyclodextrin (βββ β  β\beta -CD) were applied to 
synthesize mono - and bis	 (indolyl)methylmalononitrile derivatives by a one-pot 
three-component reaction of an aldehyde, malononitrile, and indole in an 
aqueous solution. These two inclusion complexes proved to be superior to 
CTAB or SDS individually, as cationic or anionic surfactants, respectively, 
for accessing high yields of pure products within shorter reaction times. In 
addition, simple isolation of products and mild reaction conditions are the 
other advantages of this green procedure.
                    

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Article Details

Host/guest inclusion system of surfactants with -cyclodextrin as a viable catalyst for one-pot synthesis of mono - and bis (indolyl)methylmalononitriles in H 2 O

Authors: Fatemeh MIRHASHEMI | Mohammad Ali AMROLLAHI

Publisher: TUBITAK

Main Topics: Applied physics

Journal: Turkish Journal of Chemistry 2018 Vol.42 Issue 4, pp.988-996

Document Type: Article

Publication Date: 8/2018

Document Language: English

Document ID (Org No.): 2000726031

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Fatemeh MIRHASHEMI | Mohammad Ali AMROLLAHI

Publisher:

TUBITAK

Main Topics:

Applied physics

Journal:

Turkish Journal of Chemistry 2018 Vol.42 Issue 4, pp.988-996

Document Type:

Article

Publication Date:

8/2018

Document Language:

English

Document ID (Org No.):

2000726031

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527