Adsorbent Production for Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons (PAH) in Water Samples

Mahmut Çaylar; Beyhan Tahta; Ali Burak Sünbül; Erkan Aygördü; Serhan Uruş

Article Details

Adsorbent Production for Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons (PAH) in Water Samples

Authors:

Mahmut Çaylar | Beyhan Tahta | Ali Burak Sünbül | Erkan Aygördü | Serhan Uruş

Publisher:

Osmaniye Korkut Ata Üniversitesi

Main Topics:

Kimya Mühendisliği

Journal:

Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.6 Issue 3, pp.2316-2331

Document Type:

Article

Publication Date:

4/2023

Document Language:

Turkish

Document ID (Org No.):

2001304670

pISSN:

2687-3729

Keywords:

Abstract:

 Polycyclic aromatic hydrocarbons are organic compounds with two or more aromatic rings of hydrophobic character. In addition to the studies to determine the pollution of the basins in our country, the analysis of Polycyclic Aromatic Hydrocarbons PAH is carried out intensively in the determination of the pollution of all drinking and domestic waters. C18 discs are used for PAH extraction from water samples. In this study, silica supported materials were synthesized as an alternative to C18 discs and their structures were elucidated with the synthesized adsorbent FT-IR, SEM-EDX and XRD. In addition, the obtained materials were used in the extraction and purification experiments of PAHs from water samples before HPLC analysis, and the results were compared with equivalent C18 discs. In the PAH extraction and purification experiments of the produced adsorbent, it was observed that the material synthesized with n-octadecyltrimethoxysilane C18SiO2 was even more effective than the equivalent C18 cartridges.

 Polycyclic aromatic hydrocarbons are organic compounds with two or more aromatic rings of hydrophobic character. In addition to the studies to determine the pollution of the basins in our country, the analysis of Polycyclic Aromatic Hydrocarbons PAH is carried out intensively in the determination of the pollution of all drinking and domestic waters. C18 discs are used for PAH extraction from water samples. In this study, silica supported materials were synthesized as an alternative to C18 discs and their structures were elucidated with the synthesized adsorbent FT-IR, SEM-EDX and XRD. In addition, the obtained materials were used in the extraction and purification experiments of PAHs from water samples before HPLC analysis, and the results were compared with equivalent C18 discs. In the PAH extraction and purification experiments of the produced adsorbent, it was observed that the material synthesized with n-octadecyltrimethoxysilane C18SiO2 was even more effective than the equivalent C18 cartridges.

 Polycyclic aromatic hydrocarbons are organic compounds with two or more aromatic rings of hydrophobic character. In addition to the studies to determine the pollution of the basins in our country, the analysis of Polycyclic Aromatic Hydrocarbons PAH is carried out intensively in the determination of the pollution of all drinking and domestic waters. C18 discs are used for PAH extraction from water samples. In this study, silica supported materials were synthesized as an alternative to C18 discs and their structures were elucidated with the synthesized adsorbent FT-IR, SEM-EDX and XRD. In addition, the obtained materials were used in the extraction and purification experiments of PAHs from water samples before HPLC analysis, and the results were compared with equivalent C18 discs. In the PAH extraction and purification experiments of the produced adsorbent, it was observed that the material synthesized with n-octadecyltrimethoxysilane C18SiO2 was even more effective than the equivalent C18 cartridges.

 Polisiklik aromatik hidrokarbonlar iki ya da daha fazla aromatik halkaya sahip hidrofobik karakterli organik bileşiklerdir. Ülkemizde bulunan havzaların kirliliğinin tespiti çalışmalarının yanı sıra tüm içme-kullanma sularının kirliliğinin tespitinde de Polisiklik Aromatik Hidrokarbonların PAH analizleri yoğun bir şekilde yaptırılmaktadır. Su numunelerinden PAH ekstraksiyonunda C18 diskler kullanılmaktadır. Bu çalışmada C18 disklere alternatif olarak silika destekli malzemeler sentezlendi ve sentezlenen adsorbenler FT-IR, SEM-EDX ve XRD ile yapıları aydınlatıldı. Ayrıca, elde edilen malzemeler, HPLC analizi öncesinde su numunelerinden PAH ların ekstraksiyon ve saflaştırma denemelerinde kullanıldı ve sonuçlar muadil C18 disklerle karşılaştırıldı. Üretilen adsorbenlerin PAH ekstraksiyon ve saflaştırma denemelerinde muadil C18 kartuşlar kadar hatta n-oktadesiltrimetoksisilan ile sentezlenen malzemenin C18SiO2 daha etkili bile olduğu gözlemlenmiştir.

Article Details

Adsorbent Production for Solid Phase Extraction of Polycyclic Aromatic Hydrocarbons (PAH) in Water Samples

Authors:

Mahmut Çaylar | Beyhan Tahta | Ali Burak Sünbül | Erkan Aygördü | Serhan Uruş

Publisher:

Osmaniye Korkut Ata Üniversitesi

Main Topics:

Kimya Mühendisliği

Journal:

Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.6 Issue 3, pp.2316-2331

Document Type:

Article

Publication Date:

4/2023

Document Language:

Turkish

Document ID (Org No.):

2001304670

pISSN:

2687-3729

Polyaromatic Hydrocarbon

PAH

Adsorption

Enrichment

SPE.Poliaromatik Hidrokarbon

PAH

Adsorpsiyon

Zenginleştirme

SPE.

Issues

Article Details

Authors: Mahmut Çaylar | Beyhan Tahta | Ali Burak Sünbül | Erkan Aygördü | Serhan Uruş

Publisher: Osmaniye Korkut Ata Üniversitesi

Main Topics: Kimya Mühendisliği

Journal: Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.6 Issue 3, pp.2316-2331

Document Type: Article

Publication Date: 4/2023

Document Language: Turkish

Document ID (Org No.): 2001304670

pISSN: 2687-3729

Issues

Authors:

Mahmut Çaylar | Beyhan Tahta | Ali Burak Sünbül | Erkan Aygördü | Serhan Uruş

Publisher:

Osmaniye Korkut Ata Üniversitesi

Main Topics:

Kimya Mühendisliği

Journal:

Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.6 Issue 3, pp.2316-2331

Document Type:

Article

Publication Date:

4/2023

Document Language:

Turkish

Document ID (Org No.):

2001304670

pISSN:

2687-3729