Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones

Nursabah SARIKAVAKLI; Gazi İREZ

Article Details

Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones

Authors:

Nursabah SARIKAVAKLI | Gazi İREZ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2005 Vol.29 Issue 1, pp.107-116

Document Type:

Article

Publication Date:

12/2004

Document Language:

Turkish

Document ID (Org No.):

2000729189

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

Three novel vic-dioxime compounds and their transition metal  complexes were synthesized for the first time.  These ligands are  anti-glyoximehydrazine (GH2), anti-2-pyridinealdehydeglyoxime  hydrazone (PyGH2) and anti-2-furancarboxaldehydeglyoxime hydrazone  (FGH2).  The synthesized anti-glyoximehydrazine was reacted with  2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH2 and  FGH2 ligands.  Mononuclear complexes of these ligands with a  metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II)  ions.  The structures of the ligands and complexes were determined by  1H n.m.r, i.r spectroscopy and elemental analytical techniques.

 

Three novel vic-dioxime compounds and their transition metal  complexes were synthesized for the first time.  These ligands are  anti-glyoximehydrazine (GH2), anti-2-pyridinealdehydeglyoxime  hydrazone (PyGH2) and anti-2-furancarboxaldehydeglyoxime hydrazone  (FGH2).  The synthesized anti-glyoximehydrazine was reacted with  2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH2 and  FGH2 ligands.  Mononuclear complexes of these ligands with a  metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II)  ions.  The structures of the ligands and complexes were determined by  1H n.m.r, i.r spectroscopy and elemental analytical techniques.

Article Details

Synthesis and Complex Formation of Some Novel vic-Dioxime Derivatives of Hydrazones

Authors: Nursabah SARIKAVAKLI | Gazi İREZ

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 2005 Vol.29 Issue 1, pp.107-116

Document Type: Article

Publication Date: 12/2004

Document Language: Turkish

Document ID (Org No.): 2000729189

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Nursabah SARIKAVAKLI | Gazi İREZ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2005 Vol.29 Issue 1, pp.107-116

Document Type:

Article

Publication Date:

12/2004

Document Language:

Turkish

Document ID (Org No.):

2000729189

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527