Synthesis and Characterization of 4-(Alkylaminoisonitrosoacetyl)diphenyl ether and Some of Their Metal Complexes

Ahmet COŞKUN; Funda YILMAZ

Article Details

Synthesis and Characterization of 4-(Alkylaminoisonitrosoacetyl)diphenyl ether and Some of Their Metal Complexes

Authors:

Ahmet COŞKUN | Funda YILMAZ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2008 Vol.32 Issue 3, pp.305-312

Document Type:

Article

Publication Date:

2/2008

Document Language:

Turkish

Document ID (Org No.):

2000728496

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

4-(Chloroacetyl)diphenyl ether (I) was synthesized from  chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as  catalyst in a Friedel-Crafts reaction.  Subsequently, its keto oxime  (II) derivative was prepared.  Then 3 new substituted  4-(alkylaminoisonitrosoacetyl)diphenyl ether ligands derived from  4-(phenoxy)phenyloxylohydroxymoyl chloride and corresponding amines  were synthesized.  The following aromatic and aliphatic amines were  used for the ligands ethanolamine, 2-amino-4-methylphenol, and  2-(aminomethyl) pyridine.  Mononuclear or binuclear Co(II), Ni(II),  Cu(II), and Cd(II) complexes of the ligands were synthesized.  The  structures of these ligands were identified by FT-IR, 1H-NMR, and  13C-NMR spectral data and elemental analysis, and the structures of  the complexes were identified by FT-IR, ICP-AES, elemental analysis,  and magnetic susceptibility measurements.

 

4-(Chloroacetyl)diphenyl ether (I) was synthesized from  chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as  catalyst in a Friedel-Crafts reaction.  Subsequently, its keto oxime  (II) derivative was prepared.  Then 3 new substituted  4-(alkylaminoisonitrosoacetyl)diphenyl ether ligands derived from  4-(phenoxy)phenyloxylohydroxymoyl chloride and corresponding amines  were synthesized.  The following aromatic and aliphatic amines were  used for the ligands ethanolamine, 2-amino-4-methylphenol, and  2-(aminomethyl) pyridine.  Mononuclear or binuclear Co(II), Ni(II),  Cu(II), and Cd(II) complexes of the ligands were synthesized.  The  structures of these ligands were identified by FT-IR, 1H-NMR, and  13C-NMR spectral data and elemental analysis, and the structures of  the complexes were identified by FT-IR, ICP-AES, elemental analysis,  and magnetic susceptibility measurements.

Article Details

Synthesis and Characterization of 4-(Alkylaminoisonitrosoacetyl)diphenyl ether and Some of Their Metal Complexes

Authors: Ahmet COŞKUN | Funda YILMAZ

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 2008 Vol.32 Issue 3, pp.305-312

Document Type: Article

Publication Date: 2/2008

Document Language: Turkish

Document ID (Org No.): 2000728496

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Ahmet COŞKUN | Funda YILMAZ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2008 Vol.32 Issue 3, pp.305-312

Document Type:

Article

Publication Date:

2/2008

Document Language:

Turkish

Document ID (Org No.):

2000728496

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527