Umpolung strategy: advances in catalytic C-C bond formations

Serkan EYMUR; Mehmet GÖLLÜ; Cihangir TANYELİ

Article Details

Umpolung strategy: advances in catalytic C-C bond formations

Authors:

Serkan EYMUR | Mehmet GÖLLÜ | Cihangir TANYELİ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2013 Vol.37 Issue 4, pp.586-609

Document Type:

Article

Publication Date:

3/2013

Document Language:

Turkish

Document ID (Org No.):

2000727383

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

This mini-review examines the recent advances in umpolung   strategy, devised originally by Corey and Seebach. Although numerous   stoichiometric variants have been published to date, this article covers   just the catalytic C-C bond forming reactions due to their major benefits   such as atom economy, less pollution, and workable simplicity. In the   context of umpolung, the studies are evaluated under 3 main titles: enzyme,   N-heterocyclic carbene, and cyanide ion catalyzed reactions. In particular,   enzyme and NHC catalyzed reactions mainly involve asymmetric applications.

 

This mini-review examines the recent advances in umpolung   strategy, devised originally by Corey and Seebach. Although numerous   stoichiometric variants have been published to date, this article covers   just the catalytic C-C bond forming reactions due to their major benefits   such as atom economy, less pollution, and workable simplicity. In the   context of umpolung, the studies are evaluated under 3 main titles: enzyme,   N-heterocyclic carbene, and cyanide ion catalyzed reactions. In particular,   enzyme and NHC catalyzed reactions mainly involve asymmetric applications.

Article Details

Umpolung strategy: advances in catalytic C-C bond formations

Authors: Serkan EYMUR | Mehmet GÖLLÜ | Cihangir TANYELİ

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 2013 Vol.37 Issue 4, pp.586-609

Document Type: Article

Publication Date: 3/2013

Document Language: Turkish

Document ID (Org No.): 2000727383

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Serkan EYMUR | Mehmet GÖLLÜ | Cihangir TANYELİ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2013 Vol.37 Issue 4, pp.586-609

Document Type:

Article

Publication Date:

3/2013

Document Language:

Turkish

Document ID (Org No.):

2000727383

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527