Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag2(opsp)2](NO3)2

Li-Rong WEN; Ming LI; Gui-Long ZNAO; Xue-Mei LI; Ou-Yang PINGKAI; Shu-Sheng ZHANG

Article Details

Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag2(opsp)2](NO3)2

Authors:

Li-Rong WEN | Ming LI | Gui-Long ZNAO | Xue-Mei LI | Ou-Yang PINGKAI | Shu-Sheng ZHANG

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2005 Vol.29 Issue 2, pp.193-197

Document Type:

Article

Publication Date:

1/2005

Document Language:

Turkish

Document ID (Org No.):

2000729144

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

The new silver(I) complexe [Ag2(opsp)2](NO3)2 (1) was  synthesized by the self-assembly of AgX (X = NO3-) with the  versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]-  pyrimidine).  X-ray single-crystal diffraction analyses show that 1 is  dinuclear molecule.  In 1, 1 opsp ligand acts in a bidentate mode with  2 nitrogen atoms from a pyridine ring and a pyrimidine ring  coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated  by 2 nitrogen atoms showing linear coordination geometry.

 

The new silver(I) complexe [Ag2(opsp)2](NO3)2 (1) was  synthesized by the self-assembly of AgX (X = NO3-) with the  versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]-  pyrimidine).  X-ray single-crystal diffraction analyses show that 1 is  dinuclear molecule.  In 1, 1 opsp ligand acts in a bidentate mode with  2 nitrogen atoms from a pyridine ring and a pyrimidine ring  coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated  by 2 nitrogen atoms showing linear coordination geometry.

Article Details

Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag2(opsp)2](NO3)2

Authors: Li-Rong WEN | Ming LI | Gui-Long ZNAO | Xue-Mei LI | Ou-Yang PINGKAI | Shu-Sheng ZHANG

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 2005 Vol.29 Issue 2, pp.193-197

Document Type: Article

Publication Date: 1/2005

Document Language: Turkish

Document ID (Org No.): 2000729144

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Li-Rong WEN | Ming LI | Gui-Long ZNAO | Xue-Mei LI | Ou-Yang PINGKAI | Shu-Sheng ZHANG

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2005 Vol.29 Issue 2, pp.193-197

Document Type:

Article

Publication Date:

1/2005

Document Language:

Turkish

Document ID (Org No.):

2000729144

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527