Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)

Al-Ameen Bariz Omar Ali

Article Details

Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)

Authors:

Al-Ameen Bariz Omar Ali

Publisher:

Mustansiriyah University

Journal:

Al-Mustansiriyah Journal of Science Vol.28 Issue 2, pp.48-54

Document Type:

Article

Publication Date:

1/2017

Document Language:

English

Document ID (Org No.):

2001933676

pISSN:

2521-3520

Keywords:

Abstract:

 Cyclohexane-1,2-bis(thiosemicarbazone) (CHTSC) was synthesized via the condensation reaction of cyclohexane-1,2-dione and thiosemicarbazide. Series of metal complexes of the prepared lig-and, of general formula [M(CHTSC)(NO3)2], were reported. The prepared coordination complex-es were characterized and their structures elucidated using different techniques. These showed that all complexes are octahedral geometries. The kinetics of the formation of these complexes have been investigated using stopped-flow spectrophotometry. These studies revealed that the reactions are completed on the second’s timescale with 1st-order dependence (either on the con-centration of metal salt or on the concentration of CHTSC).

Article Details

Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)

Authors:

Al-Ameen Bariz Omar Ali

Publisher:

Mustansiriyah University

Journal:

Al-Mustansiriyah Journal of Science Vol.28 Issue 2, pp.48-54

Document Type:

Article

Publication Date:

1/2017

Document Language:

English

Document ID (Org No.):

2001933676

pISSN:

2521-3520

Schiff base ligands

Thiosemicarbazones

Kinetic study

Issues

Article Details

Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)

Authors: Al-Ameen Bariz Omar Ali

Publisher: Mustansiriyah University

Journal: Al-Mustansiriyah Journal of Science Vol.28 Issue 2, pp.48-54

Document Type: Article

Publication Date: 1/2017

Document Language: English

Document ID (Org No.): 2001933676

pISSN: 2521-3520

Schiff base ligands

Thiosemicarbazones

Kinetic study

Issues

Authors:

Al-Ameen Bariz Omar Ali

Publisher:

Mustansiriyah University

Journal:

Al-Mustansiriyah Journal of Science Vol.28 Issue 2, pp.48-54

Document Type:

Article

Publication Date:

1/2017

Document Language:

English

Document ID (Org No.):

2001933676

pISSN:

2521-3520