Synthesis and spectroscopic characterization of new phthalocyanine   derivatives: application as photocatalysts for the degradation of Orange G

Yusuf YILMAZ; Kayode SANUSI

Article Details

Synthesis and spectroscopic characterization of new phthalocyanine derivatives: application as photocatalysts for the degradation of Orange G

Authors:

Yusuf YILMAZ | Kayode SANUSI

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2019 Vol.43 Issue 4, pp.1006-1016

Document Type:

Article

Publication Date:

7/2019

Document Language:

English

Document ID (Org No.):

2000725610

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

New derivatives of   2(3),9(10),16(17),23(24)-tetrakis-(6-methylpyridin-2-yloxy)phthalocyanine   (Pc) (2b, 2c, and 2d) were synthesized and their   structures were characterized by elemental analysis, IR, 11^{1}H NMR, and   high-resolution mass spectrometry. The spectral results were in line with   the proposed structures. The photodegradation of Orange G (OG) dye in DMSO   by the Pc derivatives was investigated. The compounds showed relatively high   photodegradation rates that increased with increasing size of the central   atoms. The Pc photodegradation rates showed fair correlation with the   singlet oxygen generation efficiencies (ΦΔ)ΦΔ){\Phi }_{{\Delta   }}). The observed rate constants were higher than the values already   reported for other Pcs in the literature for the photodegradation of OG in   aqueous media.

Article Details

Synthesis and spectroscopic characterization of new phthalocyanine derivatives: application as photocatalysts for the degradation of Orange G

Authors: Yusuf YILMAZ | Kayode SANUSI

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 2019 Vol.43 Issue 4, pp.1006-1016

Document Type: Article

Publication Date: 7/2019

Document Language: English

Document ID (Org No.): 2000725610

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Yusuf YILMAZ | Kayode SANUSI

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2019 Vol.43 Issue 4, pp.1006-1016

Document Type:

Article

Publication Date:

7/2019

Document Language:

English

Document ID (Org No.):

2000725610

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527