Synthesis and Characterization of [N-(4-Methoxybenzoyl amino)-thioxomethyl ]Methionine acid (MbM) and It's Complexes with Some Divalent Transition Metals Ions (Mn , Co , Ni , Cu , Zn , Cd and Hg)

Basima M. Sarhan; Rasmia M. Rumez; Murtadha A. Ali

Article Details

Synthesis and Characterization of [N-(4-Methoxybenzoyl amino)-thioxomethyl ]Methionine acid (MbM) and It's Complexes with Some Divalent Transition Metals Ions (Mn , Co , Ni , Cu , Zn , Cd and Hg)

Authors:

Basima M. Sarhan | Rasmia M. Rumez | Murtadha A. Ali

Publisher:

University of Baghdad

Journal:

Ibn AL-Haitham Journal For Pure and Applied Sciences Vol.28 Issue 1, pp.142-156

Document Type:

Article

Publication Date:

1/2015

Document Language:

English

Document ID (Org No.):

2001377297

pISSN:

2521-3407

Keywords:

Abstract:

 In this work , the ligand [N-(4-Methoxybenzoyl amino)-thioxomethyl] Methionine acid  has been synthesized by the reaction of 4- Methoxybenzoyl isothiocyanate with methionine acid . The metal complexes were prepared through the reaction of metals chlorides of Co(II) , Ni(II), Cu(II), Zn(II) and Cd(II) in ethanol as solvent . The ligand (MbM) and its metal complexes have been characterized by elemental analysis (CHNS), IR, 1H-13CNMR and UV- Vis spectra, magnetic susceptibility measurements, molar conductivity, melting points and atomic absorption. The metal-ligand ratio was determined by mole ratio method. The suggested structures for the Co(II), Ni(II), Cd(II) and Zn(II) complexes are tetrahedral geometry and  the Cu(II) complex is square planer geometry.

Article Details

Synthesis and Characterization of [N-(4-Methoxybenzoyl amino)-thioxomethyl ]Methionine acid (MbM) and It's Complexes with Some Divalent Transition Metals Ions (Mn , Co , Ni , Cu , Zn , Cd and Hg)

Authors:

Basima M. Sarhan | Rasmia M. Rumez | Murtadha A. Ali

Publisher:

University of Baghdad

Journal:

Ibn AL-Haitham Journal For Pure and Applied Sciences Vol.28 Issue 1, pp.142-156

Document Type:

Article

Publication Date:

1/2015

Document Language:

English

Document ID (Org No.):

2001377297

pISSN:

2521-3407

Methionine acid

4-methoxy benzoyl isothiocyanate

complexes

Issues

Article Details

Synthesis and Characterization of [N-(4-Methoxybenzoyl amino)-thioxomethyl ]Methionine acid (MbM) and It's Complexes with Some Divalent Transition Metals Ions (Mn , Co , Ni , Cu , Zn , Cd and Hg)

Authors: Basima M. Sarhan | Rasmia M. Rumez | Murtadha A. Ali

Publisher: University of Baghdad

Journal: Ibn AL-Haitham Journal For Pure and Applied Sciences Vol.28 Issue 1, pp.142-156

Document Type: Article

Publication Date: 1/2015

Document Language: English

Document ID (Org No.): 2001377297

pISSN: 2521-3407

Methionine acid

4-methoxy benzoyl isothiocyanate

complexes

Issues

Authors:

Basima M. Sarhan | Rasmia M. Rumez | Murtadha A. Ali

Publisher:

University of Baghdad

Journal:

Ibn AL-Haitham Journal For Pure and Applied Sciences Vol.28 Issue 1, pp.142-156

Document Type:

Article

Publication Date:

1/2015

Document Language:

English

Document ID (Org No.):

2001377297

pISSN:

2521-3407