Synthesis and Characterization of s-Triazine Cored Schiff Base Containing β-lactam and Its [M(Salen/Saloph)] (M= Cr3+ and Fe3+) Capped Complexes

Ahmed Hamdi Mirghani; Şaban Uysal

Article Details

Synthesis and Characterization of s-Triazine Cored Schiff Base Containing β-lactam and Its [M(Salen/Saloph)] (M= Cr3+ and Fe3+) Capped Complexes

Authors:

Ahmed Hamdi Mirghani | Şaban Uysal

Publisher:

Selcuk University

Main Topics:

Transition Metal Chemistry

Journal:

Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.73-79

Document Type:

Article

Publication Date:

1/2024

Document Language:

English

Document ID (Org No.):

2001327761

pISSN:

2458-9411

Keywords:

Abstract:

 This study consists of a tripodal 6-iminopenicylanic acid ligand synthesized based on the s-triazine group and its four trinuclear complexes. For this purpose, 2,4,6-trip-formylphenoxy-1,3,5-triazine III TRIPOD was obtained from the reaction of 2,4,6-trichloro-1,3,5-triazine and 4-hydroxybenzaldehyde. Then, tripodal target ligand V was obtained from the reaction of TRIPOD and 6-aminopenicylanic acid. Finally, tripodal trinuclear ML capped target complexes were obtained from the reactions of the initial complexes ML2O M Cr3 or Fe3, L Salen or Saloph with the target ligand in methanol media. The structures of all obtained ligands were elucidated using 1H NMR, FT-IR, and elemental analysis methods. The structures of the complexes were characterized using FT-IR, magnetic susceptibility, ICP-OES, and TGA methods.

 This study consists of a tripodal 6-iminopenicylanic acid ligand synthesized based on the s-triazine group and its four trinuclear complexes. For this purpose, 2,4,6-trip-formylphenoxy-1,3,5-triazine III TRIPOD was obtained from the reaction of 2,4,6-trichloro-1,3,5-triazine and 4-hydroxybenzaldehyde. Then, tripodal target ligand V was obtained from the reaction of TRIPOD and 6-aminopenicylanic acid. Finally, tripodal trinuclear ML capped target complexes were obtained from the reactions of the initial complexes ML2O M Cr3 or Fe3, L Salen or Saloph with the target ligand in methanol media. The structures of all obtained ligands were elucidated using 1H NMR, FT-IR, and elemental analysis methods. The structures of the complexes were characterized using FT-IR, magnetic susceptibility, ICP-OES, and TGA methods.

 This study consists of a tripodal 6-iminopenicylanic acid ligand synthesized based on the s-triazine group and its four trinuclear complexes. For this purpose, 2,4,6-trip-formylphenoxy-1,3,5-triazine III TRIPOD was obtained from the reaction of 2,4,6-trichloro-1,3,5-triazine and 4-hydroxybenzaldehyde. Then, tripodal target ligand V was obtained from the reaction of TRIPOD and 6-aminopenicylanic acid. Finally, tripodal trinuclear ML capped target complexes were obtained from the reactions of the initial complexes ML2O M Cr3 or Fe3, L Salen or Saloph with the target ligand in methanol media. The structures of all obtained ligands were elucidated using 1H NMR, FT-IR, and elemental analysis methods. The structures of the complexes were characterized using FT-IR, magnetic susceptibility, ICP-OES, and TGA methods.

 Bu çalışma, s-triazin grubu ve onun dört trinükleer kompleksine dayalı olarak sentezlenen tripodal 6-iminopenisilanik asit ligandından oluşmaktadır. Bu amaçla 2,4,6-trikloro-1,3,5-triazin III TRIPOD ve 4-hidroksibenzaldehitin reaksiyonundan 2,4,6-trip-formilfenoksi-1,3,5- triazin elde edildi. Daha sonra TRIPOD ve 6-aminopenisilanik asitin reaksiyonundan tripodal hedef ligandı V elde edildi. Son olarak, başlangıç komplekslerinin ML2O M Cr3 veya Fe3, L Salen veya Saloph metanol ortamında hedef ligand ile reaksiyonlarından tripodal trinükleer ML başlıklı hedef kompleksleri elde edildi. Elde edilen tüm ligandların yapıları 1H NMR, FT-IR ve elementel analiz yöntemleri kullanılarak aydınlatıldı. Komplekslerin yapıları FT-IR, manyetik duyarlılık, ICP-OES ve TGA yöntemleri kullanılarak karakterize edildi.

Article Details

Synthesis and Characterization of s-Triazine Cored Schiff Base Containing β-lactam and Its [M(Salen/Saloph)] (M= Cr3+ and Fe3+) Capped Complexes

Authors:

Ahmed Hamdi Mirghani | Şaban Uysal

Publisher:

Selcuk University

Main Topics:

Transition Metal Chemistry

Journal:

Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.73-79

Document Type:

Article

Publication Date:

1/2024

Document Language:

English

Document ID (Org No.):

2001327761

pISSN:

2458-9411

6-APA

s-triazine

salen

saloph

metal complexes6-APA

s-triazine

salen

saloph

Metal kompleksleri

Issues

Article Details

Authors: Ahmed Hamdi Mirghani | Şaban Uysal

Publisher: Selcuk University

Main Topics: Transition Metal Chemistry

Journal: Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.73-79

Document Type: Article

Publication Date: 1/2024

Document Language: English

Document ID (Org No.): 2001327761

pISSN: 2458-9411

Issues

Authors:

Ahmed Hamdi Mirghani | Şaban Uysal

Publisher:

Selcuk University

Main Topics:

Transition Metal Chemistry

Journal:

Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.73-79

Document Type:

Article

Publication Date:

1/2024

Document Language:

English

Document ID (Org No.):

2001327761

pISSN:

2458-9411