Synthesis and structural properties of NNN-3,4-(dichlorophenyl)-3-oxo-3- phenyl-2-(phenylcarbonyl)propanamide and its Cu(II) complex

Ahmet Oral SARIOĞLU; Tuğba Taşkin TOK; Mehmet AKKURT; Muhammad Nawaz TAHIR; Mehmet SÖNMEZ

Article Details

Synthesis and structural properties of NNN-3,4-(dichlorophenyl)-3-oxo-3- phenyl-2-(phenylcarbonyl)propanamide and its Cu(II) complex

Authors:

Ahmet Oral SARIOĞLU | Tuğba Taşkin TOK | Mehmet AKKURT | Muhammad Nawaz TAHIR | Mehmet SÖNMEZ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2016 Vol.40 Issue 1, pp.76-92

Document Type:

Article

Publication Date:

1/2016

Document Language:

Turkish

Document ID (Org No.):

2000726683

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

A new N-carboxamide compound (3) was synthesized by the reaction of dibenzoylaceticacid-NNN-carboxyethyla\-mide (1) and 3,4-dichloroaniline (2). The NNN-(3,4-dichlorophenyl)-3-oxo-3-phenyl-2-(phenylcarbonyl) propanamide (3) subsequently reacted with Cu salt to produce its Cu(II) complex compound (4). The compounds were characterized by analytical and spectral methods. In addition, X-ray diffraction was performed to characterize and obtain detailed information about the structure of 3. The fully optimized geometries of compounds 3 and 4 were calculated at different basis sets by using the Gaussian09 (G09) software to investigate their 3D geometries and electronic structures. Comparisons between the calculated and experimental data including molecular structures, fundamental vibrational modes, and electronic properties were made. The comparisons showed that the theoretical data were compatible with the corresponding experimental values of compounds 3 and 4.

Article Details

Synthesis and structural properties of NNN-3,4-(dichlorophenyl)-3-oxo-3- phenyl-2-(phenylcarbonyl)propanamide and its Cu(II) complex

Authors: Ahmet Oral SARIOĞLU | Tuğba Taşkin TOK | Mehmet AKKURT | Muhammad Nawaz TAHIR | Mehmet SÖNMEZ

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 2016 Vol.40 Issue 1, pp.76-92

Document Type: Article

Publication Date: 1/2016

Document Language: Turkish

Document ID (Org No.): 2000726683

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Ahmet Oral SARIOĞLU | Tuğba Taşkin TOK | Mehmet AKKURT | Muhammad Nawaz TAHIR | Mehmet SÖNMEZ

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 2016 Vol.40 Issue 1, pp.76-92

Document Type:

Article

Publication Date:

1/2016

Document Language:

Turkish

Document ID (Org No.):

2000726683

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527