Elektrokimyasal yöntemle Visinal trans-1,2-Dibromür bileşiklerinden Alken sentezi

Latif KELEBEKLİ; Yunus KARA

Article Details

Elektrokimyasal yöntemle Visinal trans-1,2-Dibromür bileşiklerinden Alken sentezi

Authors:

Latif KELEBEKLİ | Yunus KARA

Publisher:

Bingol University

Main Topics:

Applied physics

Journal:

Turkish Journal of Nature and Science 2017 Vol.6 Issue 2, pp.7-10

Document Type:

Article

Publication Date:

12/2017

Document Language:

Turkish

Document ID (Org No.):

2000655052

Frequency:

Quarterly

eISSN:

2149-6366

Abstract:

 



In this work, alkene
synthesis was carried out by electrochemical reduction of compounds having a
bicyclic ring system. The required starting compounds were prepared the
endoperoxide and trans-7,8-dibromo-cis-2,5-dihydroxybicyclo [4.2.0]
octa-3-ene using synthetic methods. Electrochemical reduction method was
applied to these compounds and obtained the cis-2,5-diacetoxy-bicyclo
[4.2.0] octa-3,7-diene and bicyclo [4.2.0] octa-3,7-diene. The structures of
all compounds obtained were determined using spectroscopic techniques (FT-IR, 1H-13C-NMR).




.

 



Bu çalışmada,
bisiklik halka sistemine sahip bileşiklerden elektrokimyasal indirgenme ile
alken sentezi yapıldı. Gerekli başlangıç bileşikleri, endoperoksit ve trans-7,8-dibromo-cis-2,5-dihidroksibisiklo [4.2.0] okta-3-en sentetik yöntemler
kullanılarak hazırlandı. Bu
bileşiklere elektrokimyasal indirgenme yöntemi uygulanarak cis-2,5-diasetoksi-bisiklo [4.2.0] okta-3,7-dien ve bisiklo [4.2.0]
okta-3,7-dien elde edildi. Elde edilen tüm bileşiklerin yapıları spektroskopik
teknikler (FT-IR, 1H- 13C-NMR) kullanılarak belirlendi.




.

Article Details

Elektrokimyasal yöntemle Visinal trans-1,2-Dibromür bileşiklerinden Alken sentezi

Authors: Latif KELEBEKLİ | Yunus KARA

Publisher: Bingol University

Main Topics: Applied physics

Journal: Turkish Journal of Nature and Science 2017 Vol.6 Issue 2, pp.7-10

Document Type: Article

Publication Date: 12/2017

Document Language: Turkish

Document ID (Org No.): 2000655052

Frequency: Quarterly

eISSN: 2149-6366

Issues

Authors:

Latif KELEBEKLİ | Yunus KARA

Publisher:

Bingol University

Main Topics:

Applied physics

Journal:

Turkish Journal of Nature and Science 2017 Vol.6 Issue 2, pp.7-10

Document Type:

Article

Publication Date:

12/2017

Document Language:

Turkish

Document ID (Org No.):

2000655052

Frequency:

Quarterly

eISSN:

2149-6366