Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Fatma Tuğçe Şenberber Dumanlı; Sibel Karaağaç; Azmi Seyhun Kıpçak; Emek Möröydor Derun

Article Details

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Authors:

Fatma Tuğçe Şenberber Dumanlı | Sibel Karaağaç | Azmi Seyhun Kıpçak | Emek Möröydor Derun

Publisher:

Turkish Chemical Society

Main Topics:

Non-Metal Chemistry | Inorganic Materials

Journal:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 2, pp.461-466

Document Type:

Article

Publication Date:

5/2024

Document Language:

English

Document ID (Org No.):

2001309566

pISSN:

2149-0120

Keywords:

Abstract:

 The effect of ultrasonic treatment on liquid-state production and the characteristic features of synthesized powder were studied in liquid-state conditions. In sonochemical synthesis, the operation parameters of mole ratio, reaction temperature, and time were optimized. The synthesis was achieved in moderate conditions such as mole ratio of copper: sodium: boron Cu: Na: B 1:2:1, 70C and 2.5 minutes. The prepared samples were identified as copper borate CuBO22 with the powder diffraction file number 00-001-0472. The reaction yields were also increased from 50 to 71.5 with the modification of the experimental procedure. The specific FT-IR peaks were observed at 1090, 985, 872, 781 and 731 cm-1 band values. In the morphological analyses, the agglomerations of multi-angular particles were seen. The results showed the affirmative effects of the possible use of the ultrasonic treatment on both the practical synthesis and the increase of characteristics.

 The effect of ultrasonic treatment on liquid-state production and the characteristic features of synthesized powder were studied in liquid-state conditions. In sonochemical synthesis, the operation parameters of mole ratio, reaction temperature, and time were optimized. The synthesis was achieved in moderate conditions such as mole ratio of copper: sodium: boron Cu: Na: B 1:2:1, 70C and 2.5 minutes. The prepared samples were identified as copper borate CuBO22 with the powder diffraction file number 00-001-0472. The reaction yields were also increased from 50 to 71.5 with the modification of the experimental procedure. The specific FT-IR peaks were observed at 1090, 985, 872, 781 and 731 cm-1 band values. In the morphological analyses, the agglomerations of multi-angular particles were seen. The results showed the affirmative effects of the possible use of the ultrasonic treatment on both the practical synthesis and the increase of characteristics.

 The effect of ultrasonic treatment on liquid-state production and the characteristic features of synthesized powder were studied in liquid-state conditions. In sonochemical synthesis, the operation parameters of mole ratio, reaction temperature, and time were optimized. The synthesis was achieved in moderate conditions such as mole ratio of copper: sodium: boron Cu: Na: B 1:2:1, 70C and 2.5 minutes. The prepared samples were identified as copper borate CuBO22 with the powder diffraction file number 00-001-0472. The reaction yields were also increased from 50 to 71.5 with the modification of the experimental procedure. The specific FT-IR peaks were observed at 1090, 985, 872, 781 and 731 cm-1 band values. In the morphological analyses, the agglomerations of multi-angular particles were seen. The results showed the affirmative effects of the possible use of the ultrasonic treatment on both the practical synthesis and the increase of characteristics.

 The effect of ultrasonic treatment on liquid-state production and the characteristic features of synthesized powder were studied in liquid-state conditions. In sonochemical synthesis, the operation parameters of mole ratio, reaction temperature, and time were optimized. The synthesis was achieved in moderate conditions such as mole ratio of copper: sodium: boron Cu: Na: B 1:2:1, 70C and 2.5 minutes. The prepared samples were identified as copper borate CuBO22 with the powder diffraction file number 00-001-0472. The reaction yields were also increased from 50 to 71.5 with the modification of the experimental procedure. The specific FT-IR peaks were observed at 1090, 985, 872, 781 and 731 cm-1 band values. In the morphological analyses, the agglomerations of multi-angular particles were seen. The results showed the affirmative effects of the possible use of the ultrasonic treatment on both the practical synthesis and the increase of characteristics.

Article Details

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Authors:

Fatma Tuğçe Şenberber Dumanlı | Sibel Karaağaç | Azmi Seyhun Kıpçak | Emek Möröydor Derun

Publisher:

Turkish Chemical Society

Main Topics:

Non-Metal Chemistry | Inorganic Materials

Journal:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 2, pp.461-466

Document Type:

Article

Publication Date:

5/2024

Document Language:

English

Document ID (Org No.):

2001309566

pISSN:

2149-0120

copper

borate

X-ray methods

spectroscopy

SEM

ultrasound

Issues

Article Details

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Authors: Fatma Tuğçe Şenberber Dumanlı | Sibel Karaağaç | Azmi Seyhun Kıpçak | Emek Möröydor Derun

Publisher: Turkish Chemical Society

Main Topics: Non-Metal Chemistry | Inorganic Materials

Journal: Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 2, pp.461-466

Document Type: Article

Publication Date: 5/2024

Document Language: English

Document ID (Org No.): 2001309566

pISSN: 2149-0120

copper

borate

X-ray methods

spectroscopy

SEM

ultrasound

Issues

Authors:

Fatma Tuğçe Şenberber Dumanlı | Sibel Karaağaç | Azmi Seyhun Kıpçak | Emek Möröydor Derun

Publisher:

Turkish Chemical Society

Main Topics:

Non-Metal Chemistry | Inorganic Materials

Journal:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 2, pp.461-466

Document Type:

Article

Publication Date:

5/2024

Document Language:

English

Document ID (Org No.):

2001309566

pISSN:

2149-0120