Reactions of N-Aminopyrimidine Derivatives with 1,3-Dicarbonyl Compounds

Zülbiye ÖNAL; Behzat ALTURAL

Article Details

Reactions of N-Aminopyrimidine Derivatives with 1,3-Dicarbonyl Compounds

Authors:

Zülbiye ÖNAL | Behzat ALTURAL

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 1999 Vol.23 Issue 4, pp.401-406

Document Type:

Article

Publication Date:

3/1999

Document Language:

Turkish

Document ID (Org No.):

2000730371

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527

Abstract:

 

The reactions of 1-Amino-pyrimidine derivatives (1) and some  1,3-dicarbonyl compounds (2) were realized in the presence of  p-toluensulfonic acid catalyst to give convenient enamine (3) and/or  imine derivatives (4).  In the same way, the enamine (5) and/or imine  derivatives (6) were synthesized using (1) and 1,3-indanedione which  is one of the different 1,3-dicarbonyl compounds.  The molecular  structures of all the prepared compounds were determined by 1H-nmr,  13C-nmr, i.r. spectra and elemental analyses, and were drawn by  taking imine-enamine tautomerism into account.

 

The reactions of 1-Amino-pyrimidine derivatives (1) and some  1,3-dicarbonyl compounds (2) were realized in the presence of  p-toluensulfonic acid catalyst to give convenient enamine (3) and/or  imine derivatives (4).  In the same way, the enamine (5) and/or imine  derivatives (6) were synthesized using (1) and 1,3-indanedione which  is one of the different 1,3-dicarbonyl compounds.  The molecular  structures of all the prepared compounds were determined by 1H-nmr,  13C-nmr, i.r. spectra and elemental analyses, and were drawn by  taking imine-enamine tautomerism into account.

Article Details

Reactions of N-Aminopyrimidine Derivatives with 1,3-Dicarbonyl Compounds

Authors: Zülbiye ÖNAL | Behzat ALTURAL

Publisher: TUBITAK

Journal: Turkish Journal of Chemistry 1999 Vol.23 Issue 4, pp.401-406

Document Type: Article

Publication Date: 3/1999

Document Language: Turkish

Document ID (Org No.): 2000730371

Frequency: Bimonthly

eISSN: 1303-6130

pISSN: 1300-0527

Issues

Authors:

Zülbiye ÖNAL | Behzat ALTURAL

Publisher:

TUBITAK

Journal:

Turkish Journal of Chemistry 1999 Vol.23 Issue 4, pp.401-406

Document Type:

Article

Publication Date:

3/1999

Document Language:

Turkish

Document ID (Org No.):

2000730371

Frequency:

Bimonthly

eISSN:

1303-6130

pISSN:

1300-0527