INSIGHT INTO THE EFFECT OF TI/ZR OXIDE HYBRID PARTICLES ON DENTAL COMPOSITES: PARTICLE SYNTHESIS AND CHARACTERIZATION AND THE MECHANICAL BEHAVIOR OF COMPOSITES

Zerin Yeşil Acar

Article Details

INSIGHT INTO THE EFFECT OF TI/ZR OXIDE HYBRID PARTICLES ON DENTAL COMPOSITES: PARTICLE SYNTHESIS AND CHARACTERIZATION AND THE MECHANICAL BEHAVIOR OF COMPOSITES

Authors:

Zerin Yeşil Acar

Publisher:

Kütahya Dumlupinar University

Main Topics:

Engineering

Journal:

Journal of Scientific Reports-A Issue 052, pp.200-219

Document Type:

Article

Publication Date:

3/2023

Document Language:

English

Document ID (Org No.):

2001282038

pISSN:

2687-6167

Keywords:

Abstract:

 Hybrid particles were synthesized with solgel-based hydrothermal method using alkoxide precursors, and the usability of these particles in dental composites was investigated. First, the effects of varying TiZr and nacid nalkoxide ratios on the crystal and microstructure of the synthesized particles Ti, Zr hybrids were investigated. X-ray diffraction XRD, a particle size and a surface charge analyzer, thermogravimetric analysis TGA, BrunauerEmmettTeller BET analysis, and Fourier transform infrared FTIR analysis were used to reveal the structural parameters. ZTit-1, ZTit-4, and ZTit-6 particles were crystalline, while ZTit-2, ZTit-3, and ZTit-5 particles were amorphous. The zeta potential of the most stable ZTit-4 particle was 43.33 mV. ZTit-3 particles had the highest surface area and ZTit-5 particles had the highest micropore area. The presence of TiZr oxide and titanate structures was determined by FTIR analysis. In the next step of the study, the mechanical behavior of the synthesized TiZr-based hybrid particles in the dental organic matrix was investigated. The flexural, compressive strengths, and microhardness of the ZTit-4 composite with optimal flowability were 17516.1 MPa, 2427.8 MPa, and 32.9 Hv.

 Hybrid particles were synthesized with solgel-based hydrothermal method using alkoxide precursors, and the usability of these particles in dental composites was investigated. First, the effects of varying TiZr and nacid nalkoxide ratios on the crystal and microstructure of the synthesized particles Ti, Zr hybrids were investigated. X-ray diffraction XRD, a particle size and a surface charge analyzer, thermogravimetric analysis TGA, BrunauerEmmettTeller BET analysis, and Fourier transform infrared FTIR analysis were used to reveal the structural parameters. ZTit-1, ZTit-4, and ZTit-6 particles were crystalline, while ZTit-2, ZTit-3, and ZTit-5 particles were amorphous. The zeta potential of the most stable ZTit-4 particle was 43.33 mV. ZTit-3 particles had the highest surface area and ZTit-5 particles had the highest micropore area. The presence of TiZr oxide and titanate structures was determined by FTIR analysis. In the next step of the study, the mechanical behavior of the synthesized TiZr-based hybrid particles in the dental organic matrix was investigated. The flexural, compressive strengths, and microhardness of the ZTit-4 composite with optimal flowability were 17516.1 MPa, 2427.8 MPa, and 32.9 Hv.

 Hybrid particles were synthesized with solgel-based hydrothermal method using alkoxide precursors, and the usability of these particles in dental composites was investigated. First, the effects of varying TiZr and nacid nalkoxide ratios on the crystal and microstructure of the synthesized particles Ti, Zr hybrids were investigated. X-ray diffraction XRD, a particle size and a surface charge analyzer, thermogravimetric analysis TGA, BrunauerEmmettTeller BET analysis, and Fourier transform infrared FTIR analysis were used to reveal the structural parameters. ZTit-1, ZTit-4, and ZTit-6 particles were crystalline, while ZTit-2, ZTit-3, and ZTit-5 particles were amorphous. The zeta potential of the most stable ZTit-4 particle was 43.33 mV. ZTit-3 particles had the highest surface area and ZTit-5 particles had the highest micropore area. The presence of TiZr oxide and titanate structures was determined by FTIR analysis. In the next step of the study, the mechanical behavior of the synthesized TiZr-based hybrid particles in the dental organic matrix was investigated. The flexural, compressive strengths, and microhardness of the ZTit-4 composite with optimal flowability were 17516.1 MPa, 2427.8 MPa, and 32.9 Hv.

 Hybrid particles were synthesized with solgel-based hydrothermal method using alkoxide precursors, and the usability of these particles in dental composites was investigated. First, the effects of varying TiZr and nacid nalkoxide ratios on the crystal and microstructure of the synthesized particles Ti, Zr hybrids were investigated. X-ray diffraction XRD, a particle size and a surface charge analyzer, thermogravimetric analysis TGA, BrunauerEmmettTeller BET analysis, and Fourier transform infrared FTIR analysis were used to reveal the structural parameters. ZTit-1, ZTit-4, and ZTit-6 particles were crystalline, while ZTit-2, ZTit-3, and ZTit-5 particles were amorphous. The zeta potential of the most stable ZTit-4 particle was 43.33 mV. ZTit-3 particles had the highest surface area and ZTit-5 particles had the highest micropore area. The presence of TiZr oxide and titanate structures was determined by FTIR analysis. In the next step of the study, the mechanical behavior of the synthesized TiZr-based hybrid particles in the dental organic matrix was investigated. The flexural, compressive strengths, and microhardness of the ZTit-4 composite with optimal flowability were 17516.1 MPa, 2427.8 MPa, and 32.9 Hv.

Article Details

INSIGHT INTO THE EFFECT OF TI/ZR OXIDE HYBRID PARTICLES ON DENTAL COMPOSITES: PARTICLE SYNTHESIS AND CHARACTERIZATION AND THE MECHANICAL BEHAVIOR OF COMPOSITES

Authors:

Zerin Yeşil Acar

Publisher:

Kütahya Dumlupinar University

Main Topics:

Engineering

Journal:

Journal of Scientific Reports-A Issue 052, pp.200-219

Document Type:

Article

Publication Date:

3/2023

Document Language:

English

Document ID (Org No.):

2001282038

pISSN:

2687-6167

ZrO2–TiO2

Mixed oxide

Sol–gel

Composite

Flowability

Microhardness

Issues

Article Details

INSIGHT INTO THE EFFECT OF TI/ZR OXIDE HYBRID PARTICLES ON DENTAL COMPOSITES: PARTICLE SYNTHESIS AND CHARACTERIZATION AND THE MECHANICAL BEHAVIOR OF COMPOSITES

Authors: Zerin Yeşil Acar

Publisher: Kütahya Dumlupinar University

Main Topics: Engineering

Journal: Journal of Scientific Reports-A Issue 052, pp.200-219

Document Type: Article

Publication Date: 3/2023

Document Language: English

Document ID (Org No.): 2001282038

pISSN: 2687-6167

ZrO2–TiO2

Mixed oxide

Sol–gel

Composite

Flowability

Microhardness

Issues

Authors:

Zerin Yeşil Acar

Publisher:

Kütahya Dumlupinar University

Main Topics:

Engineering

Journal:

Journal of Scientific Reports-A Issue 052, pp.200-219

Document Type:

Article

Publication Date:

3/2023

Document Language:

English

Document ID (Org No.):

2001282038

pISSN:

2687-6167