Zirconium Sulfate as Catalyst for Biodiesel Production by Using Reactive Distillation

Wadood Taher Mohammed; Marwa Faeq Abdul Jabbar

doi:10.31026/j.eng.2016.01.05

Article Details

Zirconium Sulfate as Catalyst for Biodiesel Production by Using Reactive Distillation

Authors:

Wadood Taher Mohammed | Marwa Faeq Abdul Jabbar

Publisher:

University of Baghdad

Journal:

Journal of Engineering Vol.22 Issue 1, pp.68-82

Document Type:

Article

Publication Date:

1/2016

Document Language:

English

Document ID (Org No.):

2001380988

pISSN:

2520-3339

DOI:

10.31026/j.eng.2016.01.05

Keywords:

Abstract:

 Production of fatty acid esters (biodiesel) from oleic acid and 2-ethylhexanol using sulfated zirconia as solid catalyst for the production of biodiesel was investigated in this work.
 
       The parameters studied were temperature of reaction (100 to 130°C), molar ratio of alcohol to free fatty acid (1:1 to 3:1), concentration of catalyst (0.5 to 3%wt), mixing speed (500 to 900 rpm) and types of sulfated zirconia (i.e modified, commercial, prepared  catalyst according to literature and reused catalyst). The results show the best conversion to biodiesel was 97.74% at conditions of 130°C, 3:1, 2wt% and 650 rpm using modified catalyst respectively. Also, modified catalyst gave identical results to that of commercial one. Simulation study was adopted from basic principles of reactive distillation and the results were close to an acceptable degree.

Article Details

Zirconium Sulfate as Catalyst for Biodiesel Production by Using Reactive Distillation

Authors:

Wadood Taher Mohammed | Marwa Faeq Abdul Jabbar

Publisher:

University of Baghdad

Journal:

Journal of Engineering Vol.22 Issue 1, pp.68-82

Document Type:

Article

Publication Date:

1/2016

Document Language:

English

Document ID (Org No.):

2001380988

pISSN:

2520-3339

DOI:

10.31026/j.eng.2016.01.05

biodiesel

reactive distillation

sulfated zirconia

heterogeneous catalyst

Issues

Article Details

Zirconium Sulfate as Catalyst for Biodiesel Production by Using Reactive Distillation

Authors: Wadood Taher Mohammed | Marwa Faeq Abdul Jabbar

Publisher: University of Baghdad

Journal: Journal of Engineering Vol.22 Issue 1, pp.68-82

Document Type: Article

Publication Date: 1/2016

Document Language: English

Document ID (Org No.): 2001380988

pISSN: 2520-3339

DOI: 10.31026/j.eng.2016.01.05

biodiesel

reactive distillation

sulfated zirconia

heterogeneous catalyst

Issues

Authors:

Wadood Taher Mohammed | Marwa Faeq Abdul Jabbar

Publisher:

University of Baghdad

Journal:

Journal of Engineering Vol.22 Issue 1, pp.68-82

Document Type:

Article

Publication Date:

1/2016

Document Language:

English

Document ID (Org No.):

2001380988

pISSN:

2520-3339

DOI:

10.31026/j.eng.2016.01.05